How to Print Avery Labels in Microsoft Word on PC or Mac - wikiHow Step 1, Open a blank Microsoft Word document. Microsoft Word now makes it very easy to create an Avery-compatible label sheet from within the app. If you already have Microsoft Word open, click the File menu, select New, and choose Blank to create one now. If not, open Word and click Blank on the New window.Step 2, Click the Mailings tab. It's at the top of Word.[1] X Trustworthy Source Microsoft Support Technical support and product information from Microsoft. Go to sourceStep 3, Click ...